Publications [#234201] of Eric J. Toone

Journal Articles

  1. Stamler, JS; Toone, EJ, "The decomposition of thionitrites.", Current opinion in chemical biologyDecember,, 2002, 6(6), 779-785 [12470731], [doi].
    (last updated on 2024/03/28)

    Abstract:
    The mechanism of thionitrite decomposition, both in vivo and in vitro, remains unclear. Thionitrite stability is highly variable; it is a complex function of thionitrite structure and environmental condition. Several recent advances clarify the role of unimolecular homlytic decomposition, metal-catalyzed reductive decomposition and higher-order enzymatic and non-enzymatic processes to the overall observed stability of thionitrites.