Publications [#232167] of Stephen L. Craig

Papers Published

  1. Craig, SL, "From ionic liquids to supramolecular polymers.", Angewandte Chemie International Edition, 2009, 48(15), 2645-2647 [19222061], [doi].
    (last updated on 2017/11/19)

    Abstract:
    Charging forward: Ionic interactions presented in a multivalent fashion in small-molecule ionic liquids lead to functional polymer-like materials (see picture) that are consistent with the formation of a supramolecular ionic network. For example, the ionic material formed from a dication consisting of two covalently linked tetraalkyl phosphonium moieties and a porphyrin tetracarboxylate has a viscosity of 10(6) Pa s at 25 degrees C.