Publications [#322170] of Steven Malcolmson

Journal Articles

  1. Logan, AWJ; Theis, T; Colell, JFP; Warren, WS; Malcolmson, SJ, "Hyperpolarization of Nitrogen-15 Schiff Bases by Reversible Exchange Catalysis with para-Hydrogen.", Chemistry (Weinheim an der Bergstrasse, Germany)July,, 2016, 22(31), 10777-10781 [doi].
    (last updated on 2024/03/28)

    Abstract:
    NMR with thermal polarization requires relatively concentrated samples, particularly for nuclei with low abundance and low gyromagnetic ratios, such as (15) N. We expand the substrate scope of SABRE, a recently introduced hyperpolarization method, to allow access to (15) N-enriched Schiff bases. These substrates show fractional (15) N polarization levels of up to 2 % while having only minimal (1) H enhancements.