Publications [#285315] of Amanda Hargrove

Journal Articles

  1. Spence, JD; Hargrove, AE; Crampton, HL; Thomas, DW, "Porphyrenediynes: synthesis and cyclization of meso-enediynylporphyrins", Tetrahedron LettersJanuary,, 2007, 48(4), 725-728, Elsevier BV [doi].
    (last updated on 2021/09/20)

    Abstract:
    Synthetic methodology to prepare porphyrinylethynyl enediynes has been developed. Compared to phenylethynyl derivatives, a bulky porphyrinic substituent on the alkyne significantly increases the thermal barrier toward Bergman cyclization and leads to multiple photolysis products. © 2006.