Publications [#233208] of Andrew T. McPhail
Journal Articles
- Reichard, GA; Spitler, J; Mergelsberg, I; Miller, A; Wong, G; Raghavan, R; Jenkins, J; Gan, T; McPhail, AT, "The asymmetric synthesis of (3R)-N-methyl-2-oxo-[1,4′-bipiperidine]-3-acetamide in quantity", Tetrahedron AsymmetryJune,, 2002, 13(9), 939-943, Elsevier BV [Gateway.cgi], [doi].
(last updated on 2026/01/21)Abstract:
The asymmetric synthesis of the enantiomerically pure bipiperidine core fragment of a potent dual NK1 /NK2 antagonist is described. The utilization of a diastereoselective Michael addition employing Evans' auxiliary as the key step allowed for the preparation of the fragment on a multi-kilogram scale. © 2002 Published by Elsevier Science Ltd.