Publications [#233323] of Andrew T. McPhail

Journal Articles

  1. Porter, NA; Wu, WX; McPhail, AT, "Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions", Tetrahedron LettersFebruary,, 1991, 32(6), 707-710, Elsevier BV [Gateway.cgi], [doi].
    (last updated on 2026/01/21)

    Abstract:
    Competition rate constants were determined for the addition of cyclohexyl radical to α,β unsaturated amides derived from pyrrolidine and trans-2,5-dimethylpyrrolidine. The relative rates can be understood by single crystal X-Ray analyses of the alkenes and an examination of the presumed transition state. © 1991.