Publications [#233345] of Andrew T. McPhail

Journal Articles

  1. Scott, DM; McPhail, AT; Porter, NA, "Highly stereoselective radical addition to a trisubstituted alkene by low temperature photolysis of thiohydroxamic esters", Tetrahedron LettersJanuary,, 1990, 31(12), 1679-1682, Elsevier BV [Gateway.cgi], [doi].
    (last updated on 2026/01/21)

    Abstract:
    Low temperature carbon radical addition to α,β-unsaturated amides of trans-2,5-dimethylpyrrolidine was achieved in high yield with high diastereoselectivity by photolysis of Barton esters. Use of an olefin substituted with three electron withdrawing groups provides synthetic versatility and regiospecificity. © 1990.