Publications [#233346] of Andrew T. McPhail

Journal Articles

  1. Lukehart, CM; McPhail, AT; McPhail, DR; Owen, MD, "Transformation of O2S(C≡CCMe3)2 to an exoalkylidene thiete 1,1-dioxide ligand by Pt-H addition and rearrangement reactions", Journal of the Chemical Society Chemical CommunicationsDecember,, 1990(3), 215-217, Royal Society of Chemistry (RSC) [Gateway.cgi], [doi].
    (last updated on 2026/01/21)

    Abstract:
    Addition of a Pt-H bond to the C≡C bond of an alkynyl substituent of a dialkynylsuiphone occurs regioselectively to give an exoalkylidene thiete 1, 1-dioxide ligand following a subsequent insertion and rearrangement of the second alkynyl substituent; a proposed mechanism for the unusual formation of the heterocyclic ligand is presented.