Publications [#233364] of Andrew T. McPhail

Journal Articles

  1. Clark, TJ; Nile, TA; McPhail, D; McPhail, AT, "Synthesis of novel substituted cyclopentadienes and their early transition metal complexes", PolyhedronJanuary,, 1989, 8(13-14), 1804-1806, Elsevier BV [Gateway.cgi], [doi].
    (last updated on 2026/01/21)

    Abstract:
    Synthesis of two substituted cyclopentadienes, 1,3-bis(1-methylcyclohexyl) cyclopentadiene, Cp′H and [2-methyl-2-(2-pyridyl)ethyl]cyclopentadiene, Cp″H from fulvene intermediates is reported. These are readily converted to their early transition metal complexes Cp′W(CO)3Me, Cp″Mo(CO)3Me, CP″W(CO)3Me and [Cp″Ti(O)Cl·CH2Cl2]2. The X-ray crystal structure of the titanium compound shows that the nitrogen of the pyridine cyclopentadienyl substituent is coordinated to the titanium. © 1989.