Publications [#233398] of Andrew T. McPhail

Journal Articles

  1. Wells, RL; Purdy, AP; Higa, KT; McPhail, AT; Pitt, CG, "Synthesis and characterization of a dimeric tris(arsino)gallane containing a nonplanar (Ga-As)2 ring: crystal structure of {[(Me3SiCH2)2As]3Ga}2", Journal of Organometallic ChemistryMay,, 1987, 325(1-2), C7-C10, Elsevier BV [Gateway.cgi], [doi].
    (last updated on 2026/01/21)

    Abstract:
    The dimer {[(Me3SiCH2)2As]3Ga}2, only the second tris(arsino)gallane to be completely characterized, has been prepared by the reaction of (Me3SiCH2)2AsLi with GaCl3; X-ray crystallographic analysis shows it to be the first example of a compound containing a distinctly nonplanar four-membered ring of alternating four-coordinate Ga and As atoms. © 1987.