Publications [#233422] of Andrew T. McPhail
Journal Articles
- Wenkert, D; Ferguson, SB; Porter, B; Qvarnstrom, A; McPhail, AT, "Thermal Transformation of Alkenoylated Aziridines into Ring-Fused Pyrrolidines", Journal of Organic ChemistryJanuary,, 1985, 50(21), 4114-4119, American Chemical Society (ACS) [Gateway.cgi], [doi].
(last updated on 2026/01/21)Abstract:
3-Phenyl- and 3-unsubstituted-2-alkenoyl-1-methylaziridines have been synthesized via Grignard reactions with the corresponding 2-cyanoaziridines. The 3-phenylated-2-alkenoylaziridines have been thermally transformed into ring-fused pyrrolidine compounds. The configurations and conformations of the aziridine and pyrrolidine compounds have been determined by 1H and 13C NMR spectroscopy and X-ray crystallography. © 1985, American Chemical Society. All rights reserved.