Publications [#233468] of Andrew T. McPhail

Journal Articles

  1. Brambilla, R; Friary, R; Ganguly, A; Puar, MS; Sunday, BR; Wright, JJ; Onan, KD; McPhail, AT, "Intramolecular Cycloadditions of Nitrones Joined by Amides to Olefins", Tetrahedron, 1981, 37(21), 3615-3625, Elsevier BV [Gateway.cgi], [doi].
    (last updated on 2026/01/21)

    Abstract:
    Six nitrones joined by amides to olefins were prepared in situ from the related ketones 1-3 with N-methy]- and benzylhydroxylamines. The nitrones added intramolecularly to the olefins, and the cycloadditions gave the 6-lactams 4-9 stereoselectively and regiospecifically. Chemical correlations, CMR spectroscopy and two X-ray crystallographic analyses established that the relative stereochemistries of the six cycloadducts 4-9 were identical. © 1981.