Publications [#233471] of Andrew T. McPhail

Journal Articles

  1. Saksena, AK; McPhail, AT; Onan, KD, "Carbocyclic analogs of C-nucleosides: a key intermediate via a novel and efficient CC ring scission", Tetrahedron LettersJanuary,, 1981, 22(22), 2067-2070, Elsevier BV [Gateway.cgi], [doi].
    (last updated on 2026/01/21)

    Abstract:
    Treatment of hydroxymethylene ketone 6 with trimethylene dithiotosylate according to literature conditions,3b led to the novel CC ring scission product 7 in high yield; also, the hydroxide-initiated cleavage4 of 1 gave the β-elimination product 13 which underwent a highly stereospecific addition of diazomethane to provide 15. © 1981.