Publications [#233558] of Andrew T. McPhail

Journal Articles

  1. Crumbliss, AL; Gestaut, LJ; Rickard, RC; McPhail, AT, "Preparation and X-ray crystal structure of a novel tetranuclear copper(I) ethylenethiourea cluster complex, μ4-ethylenethiourea-cyclo- tetrakis-μ-(ethylenethiourea)tetrakis[ethylenethioureacopper(I)] nitrate hexahydrate", Journal of the Chemical Society Chemical CommunicationsJanuary,, 1974(14), 545-546, Royal Society of Chemistry (RSC) [doi].
    (last updated on 2026/01/21)

    Abstract:
    The structure, geometry, and bonding in [Cu4(C3H 6N2S)9(NO3)4],6H 2O have been established by X-ray analysis which reveals discrete Cu4(C3H6N2S)9 4+ cations containing an alternating Cu-S eight-membered ring with a unique ethylenethiourea ligand in an axial position bridging four copper atoms.