Publications [#234816] of Benjamin J. Wiley
Journal Articles
- Sang, HI; Yun, TL; Wiley, B; Xia, Y, "Large-scale synthesis of silver nanocubes: The role of HCl in promoting cube perfection and monodispersity", Angewandte Chemie - International EditionMarch,, 2005, 44(14), 2154-2157, WILEY [doi].
(last updated on 2024/11/19)Abstract:
(Chemical Equation Presented) One lump or two! Selective etching of twinned seeds, mediated by HCl and the oxygen in air, resulted in high yields of perfect single-crystal silver nanocubes in a range of sizes (30-130 nm). The chloride ion enhances oxidation and prevents aggregation, while the proton decreases the rate of reduction and facilitates etching through the formation of nitric acid. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.