Publications [#232027] of David N. Beratan

Journal Articles

  1. Onuchic, JN; Beratan, DN, "Molecular Bridge Effects on Distant Charge Tunneling", Journal of the American Chemical SocietyOctober,, 1987, 109(22), 6771-6778, American Chemical Society (ACS) [pdf], [doi].
    (last updated on 2024/04/23)

    Abstract:
    The question arises as to whether different hydrocarbon bridges should give different electron-transfer rates. We answer this question on the basis of energetic and topological (interference) effects that can be gleaned from one-electron models. A discussion of model compound electron-transfer rates based on this interpretation is given. The approximations implicit in the periodic models used here (and in previous work) are carefully justified. © 1987, American Chemical Society. All rights reserved.