Publications [#232726] of Katherine J. Franz

Journal Articles

  1. Franz, KJ; Singh, N; Lippard, SJ, "Metal-based NO sensing by selective ligand dissociation", Angewandte Chemie International Edition, 2000, 39(12), 2120-2122, WILEY [doi].
    (last updated on 2023/01/01)

    Abstract:
    Nitric oxide reacts selectively with the O2 stable, weakly fluorescent complex [Co(DATI-4)] in dichloromethane solution to dissociate a fluorophore- substituted arm of the aminotroponiminate ligand DATI-4. The resulting cobalt-dinitrosyl adduct (see picture) effects a positive fluorescence response. The detection limit of 2 is 50-100 μm for NO.