Publications [#233742] of Richard A. Palmer

Journal Articles

  1. Kirby, AF; Palmer, RA, "Single-Crystal Electronic Absorption of Tris(1,3-diphenyl-1,3-propanedionato)aquoneodymium(III): Oscillator Strength of the 4I9/2→4G5/2 Hypersensitive Transition", Inorganic ChemistryJanuary,, 1981, 20(4), 1030-1033, American Chemical Society (ACS) [Gateway.cgi], [doi].
    (last updated on 2024/07/16)

    Abstract:
    The ligand polarization model is examined for the calculation of f → f electronic intensity in the 4I9/2 → 4G5/2 hypersensitive transition of tris(1,3-diphenyl-1,3-propanedionato)aquoneodymium(III). The electronic oscillator strengths of the single crystal are found experimentally and used in the determination of the phenomenological parameters of the Judd-Ofelt equation. Theoretical hypersensitive intensity calculations are based on X-ray structural data and average ligand polarizabilities and are compared to experimental values. © 1981, American Chemical Society. All rights reserved.