| Publications [#266640] of A Ronald Gallant
Journal Articles
- NPC Chao, JA Cuculo, AR Gallant and TW George, STATISTICAL METHOD FOR DETERMINING THE GLASS TRANSITION TEMPERATURE FROM DILATOMETRIC DATA.,
Appl Polym Symp no. 27
(1975),
pp. 193-204
(last updated on 2016/06/24)
Abstract: An objective procedure for estimating the glass transition temperature (T//g) from dilatometric data is described. The method uses the technique of fitting a segmented linear regression model by least squares. The regression model employed may be specified so as to allow a transition either of the first order in the thermodynamic sense or may be constrained to fit a second order. Methods are given for finding statistical confidence intervals for the estimated glass transition temperature (T//g). Experimental data obtained from PET (polyethylene terephthalate) fiber are used for illustration; these data indicate a preference for the second-order transition model. 8 refs.
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