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Math @ Duke
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Publications [#363593] of Sayan Mukherjee
Papers Published
- Sahoo, H; Mukherjee, S; Grandhi, GS; Selvakumar, J; Baidya, M, Copper Catalyzed C-N Cross-Coupling Reaction of Aryl Boronic Acids at Room Temperature through Chelation Assistance.,
The Journal of organic chemistry, vol. 82 no. 5
(March, 2017),
pp. 2764-2771 [doi]
(last updated on 2025/04/11)
Abstract: A copper-catalyzed selective C-N cross-coupling has been developed based on chelation-assisted amidation of readily available aryl boronic acids at room-temperature under open-flask conditions. The reaction is scalable and tolerates a wide spectrum of functional groups delivering fully substituted unsymmetrical amides in high yields (up to 96%). The C-N cross coupling also established with aryl silanes, extending the palette of coupling partners of this strategy.
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