Publications [#285315] of Amanda Hargrove

Journal Articles

1. Spence, JD; Hargrove, AE; Crampton, HL; Thomas, DW, Porphyrenediynes: synthesis and cyclization of meso-enediynylporphyrins, Tetrahedron Letters, vol. 48 no. 4 (January, 2007), pp. 725-728, Elsevier BV, ISSN 0040-4039 [doi]
   (last updated on 2024/12/31)

   Abstract:
   Synthetic methodology to prepare porphyrinylethynyl enediynes has been developed. Compared to phenylethynyl derivatives, a bulky porphyrinic substituent on the alkyne significantly increases the thermal barrier toward Bergman cyclization and leads to multiple photolysis products. © 2006.