Publications [#234201] of Eric J. Toone

Journal Articles

1. Stamler, JS; Toone, EJ, The decomposition of thionitrites., Current opinion in chemical biology, vol. 6 no. 6 (December, 2002), pp. 779-785, ISSN 1367-5931 [12470731], [doi]
   (last updated on 2026/01/13)

   Abstract:
   The mechanism of thionitrite decomposition, both in vivo and in vitro, remains unclear. Thionitrite stability is highly variable; it is a complex function of thionitrite structure and environmental condition. Several recent advances clarify the role of unimolecular homlytic decomposition, metal-catalyzed reductive decomposition and higher-order enzymatic and non-enzymatic processes to the overall observed stability of thionitrites.