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| Publications [#332147] of Jie Liu
search www.chem.duke.edu.Journal Articles
- Jiang, S; Zhang, H; Song, S; Ma, Y; Li, J; Lee, GH; Han, Q; Liu, J, Highly Stretchable Conductive Fibers from Few-Walled Carbon Nanotubes Coated on Poly(m-phenylene isophthalamide) Polymer Core/Shell Structures.,
ACS nano, vol. 9 no. 10
(October, 2015),
pp. 10252-10257 [doi]
(last updated on 2026/01/16)
Abstract: A core/shell stretchable conductive composite of a few-walled carbon nanotube network coated on a poly(m-phenylene isophthalamide) fiber (FWNT/PMIA) was fabricated by a dip-coating method and an annealing process that greatly enhanced interactions between the FWNT network and PMIA core as well as within the FWNT network. The first strain-conductivity test of the as-prepared FWNT/PMIA fiber showed a stretching-induced alignment of nanotubes in the shell during the deformation process and a good conductivity stability with a slight conductivity drop from 109.63 S/cm to 98.74 S/cm (Δσ/σ0 = 10%) at a strain of ∼150% (2.5 times the original length). More importantly, after the first stretching process, the fiber can be recovered with a slight increase in length but a greatly improved conductivity of 167.41 S/cm through an additional annealing treatment. The recovered fiber displays a similarly superb conductivity stability against stretching, with a decrease of only ∼13 S/cm to 154.49 S/cm (Δσ/σ0 = 8%) at a strain of ∼150%. We believe that this conductivity stability came from the formation and maintaining of aligned nanotube structures during the stretching process, which ensures the good tube-tube contacts and the elongation of the FWNT network without losing its conductivity. Such stable conductivity in stretchable fibers will be important for applications in stretchable electronics.
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