Publications [#234088] of Michael J. Therien

Papers Published

1. De Rege, PJF; Therien, MJ, Synthesis of (porphinato)zinc(II)-spacer-(porphinato)iron(III) chloride complexes: A modular approach to fixed-distance electron-transfer model compounds through the efficacy of metal-mediated cross-coupling, Inorganica Chimica Acta, vol. 242 no. 1-2 (February, 1996), pp. 211-218, Elsevier BV [doi]
   (last updated on 2026/01/15)

   Abstract:
   The syntheses of (porphinato)zinc(II)-spacer-(porphinato)iron(III) chloride complexes were effected by the agency of Pd-catalyzed cross-coupling of two equivalents of [5-bromo-10,20-diphenyl-15-(4′-methoxyphenyl)porphinato]zinc with a symmetric bis(trimethyltin) derivative of a rigid organic spacer molecule, followed by a demetalation-remetalation reaction sequence. The approach described herein represents a new strategy for assembling porphyrin-based donor-spacer-acceptor compounds that is predicated on the modular syntheses of rigid donor, acceptor, and spacer molecules.