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| Publications [#263008] of Tuan Vo-Dinh
Papers Published
- Bello, JM; Anantha Narayanan, V; Vo Dinh, T, Surface-enhanced Raman scattering interaction of p-aminobenzoic acid on a silver-coated alumina substrate,
Spectrochim. Acta A, Mol. Spectrosc. (UK), vol. 48A no. 4
(1992),
pp. 563-567, Elsevier BV, ISSN 0584-8539 [0584-8539(92)80047-Z], [doi]
(last updated on 2026/01/21)
Abstract: The adsorption behavior of p-aminobenzoic acid (PABA) molecules on a silver-coated alumina surface-enhanced Raman scattering (SERS) substrate was investigated. For spotted PABA and PABA in non-polar solvents, the PABA molecule is adsorbed flat on the surface of the SERS substrate. In this orientation, the benzene ring is π-bonded to the substrate, and the molecule is further anchored to the substrate by the binding of the lone pairs of NH2 and COO- groups onto the metal surface. On the other hand, the adsorption behavior of PABA in a polar solvent is greatly influenced by the hydrogen bonding of the amine group with the polar solvent. In this orientation, the molecule is preferentially adsorbed through the COO- and assumes a nonflat orientation on the metal surface
Keywords: adsorbed layers;alumina;organic compounds;silver;surface enhanced Raman scattering;
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