Publications [#285327] of Christopher P. Roy

Journal Articles

1. Merola, JS; Roy, CP, Hydrido(prolinato-κ² N,O)tris(trimethylphosphane-κP) iridium(III) hexafluoridophosphate, Acta Crystallographica Section E: Structure Reports Online, vol. 70 no. 2 (February, 2014), pp. m73-m74, ISSN 1600-5368 [doi]
   (last updated on 2022/07/06)

   Abstract:
   The title complex, [Ir(C5H8NO2)H(C3H9P)3]PF6, has two independent anion-cation pairs in the asymmetric unit. The geometry about each Ir III atom is pseudo-octahedral with a meridional arrangement of the P(CH3)3 ligands, N,O-bidentate coordination of prolinate and a hydride ligand trans to the prolinate N atom. The independent IrIII moieties are joined by N - HO hydrogen bonds and the N - HO bonding motif continues throughout the structure, creating an extended chain parallel to the c-axis direction. The methyl groups of one P(CH3)3 ligand are rotationally disordered over two sets of sites in a 0.62(2):0.38(2) ratio. © Merola and Roy 2014.